Dulce de Leche and Chocolate Chunk Bread Pudding
['8 1/2-inch-thick slices egg bread (about 4 x 5 inches), crusts trimmed, cut into 3/4- to 1-inch cubes', '4 tablespoons (1/2 stick) unsalted butter, melted, divided', '1 1/2 cups heavy whipping cream', '1 cup purchased dulce de leche ice cream topping or butterscotch-caramel sauce plus more for serving', '4 large eggs', '2 large egg yolks', '2 tablespoons dark rum', '1 teaspoon vanilla extract', 'Pinch of salt', '1/2 cup (about 3 ounces) bittersweet chocolate chips', '2 tablespoons sugar', 'Powdered sugar']
Preheat oven to 350°F. Place bread in large bowl. Drizzle with 3 tablespoons melted butter; toss. Transfer to rimmed baking sheet. Bake until bread begins to color, stirring occasionally, about 12 minutes. Cool. Brush 11x7x2-inch glass baking dish with 1 tablespoon melted butter.
Stir whipping cream and 1 cup dulce de leche in medium saucepan over medium heat until blended and bubbling. Remove from heat. Whisk eggs and yolks in large bowl. Add rum, vanilla, and salt; gradually whisk in warm dulce de leche mixture. Stir in bread cubes. Let soak 30 minutes, stirring occasionally.
Mix chocolate chips into custard mixture. Pour into prepared dish. Sprinkle with 2 tablespoons sugar. Bake pudding until puffed and set in center, about 35 minutes. Let cool 15 minutes. Dust with powdered sugar. Serve warm, passing more dulce de leche topping alongside.
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