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Pecan and Chocolate Pralines

['2 cups pecan halves plus 24 for garnish', '1 cup sugar', '1 cup (packed) light brown sugar', '1/2 cup heavy cream', '2 tablespoons (1/4 stick) unsalted butter', '4 ounces semisweet or bittersweet chocolate, melted', 'A candy thermometer']

Line 2 baking sheets with parchment. Stirring gently, bring 2 cups pecans, both sugars, cream, and butter to a boil in a medium heavy saucepan over medium-high heat. Attach candy thermometer to side of pan. Boil, occasionally swirling pan, until thermometer registers 236°F, 7-8 minutes. Remove from heat; stir vigorously with a wooden spoon until mixture thickens and pecans are suspended in syrup, 2-3 minutes.
Drop candy by heaping teaspoonfuls onto prepared sheets. Let cool completely. Spoon some melted chocolate over; place a pecan half on top. Chill until set, about 30 minutes. DO AHEAD: Can be made 1 week ahead. Store airtight in refrigerator. Return to room temperature before serving.

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